An 1849 engraving depicting a will-o’-the-wisp
SSPL/Getty Photographs
Bubbles merging in water can spontaneously generate electrical sparks highly effective sufficient to ignite methane, which may clarify mysterious flashes of sunshine generally known as will-o’-the-wisps.
In bogs, swamps and marshes, folks often see mysterious blue-tinged flashes of sunshine above water, which have generally been related to ghosts or spirits. A extra seemingly rationalization for these will-o’-the-wisps, or ignis fatuus, is that the flashes come from the combustion of gases, like methane and phosphine, produced by decaying natural matter within the murky water beneath. However it’s unclear what would make the gases ignite, with proposed causes equivalent to static electrical energy or lightning remaining unproven.
Now, Richard Zare at Stanford College in California and his colleagues have noticed spontaneous electrical sparks between bubbles of methane and air in water within the laboratory, which they name microlightning. They are saying such occasions may simply have sufficient vitality to ignite methane fuel.
“We proceed to find issues about water that, when you perceive them, they’re apparent, however earlier than then, they appear utterly weird,” says Zare. “Nobody thinks of water associated to fireside. They suppose water places out hearth. They’re not telling you with water, I can get a spark and set one thing on hearth. That is new.”
Zare and his colleagues had already seen water droplets, the scale of a grain of salt, build up cost and spontaneously creating sparks, in order that they thought the same impact may happen between methane bubbles in water. They used a nozzle to ship microbubbles of methane combined with air by means of water and noticed the place the bubbles would collide utilizing a high-speed digital camera, in addition to a photon counter and spectrometer.
Because the bubbles rose by means of the water, they modified form and amassed cost. When two bubbles met, the distinction in cost between them would trigger a spark, producing a flash that Zare and his staff recorded with each the digital camera and photon counter.
Additionally they measured the frequencies of sunshine within the flash, and located they matched the signature of particular compounds that had been chemically excited. This implies the sparks can be highly effective sufficient to set off the ignition of a fuel like methane.

Microlightning between bubbles containing air and methane
Yu Xia
“[The Italian physicist Alessandro] Volta first speculated that it was lightning inflicting these ignis fatuus, and in some sense he was proper, however not for the explanations he thought,” says Zare. “It’s not lightning within the air coming from the sky; it’s actually from the droplets.”
“It clearly seems to be very attention-grabbing,” says Detlef Lohse on the College of Twente within the Netherlands. Whereas it isn’t a definitive interpretation of what’s inflicting will-o’-the-wisps, it’s a believable chance, says Lohse, and the outcomes are prone to spark additional investigation.
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